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Wetting and Growth Behaviors in Adsorbed Systems with Long-Range Forces

机译:长距离吸附系统中的润湿和生长行为

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摘要

The growth and possible wetting behaviors of an adsorbed film are studied employing a solid-on-solid model in the presence of a hard wall and external potential V(h) which is of long range. The model is analyzed with the use of position-space renormalization-group methods within the Migdal approximation. The existence of wetting transitions and their nature depends on the asymptotic behavior of V(h) at large distances. We find that critical wetting cannot take place in this model. From what is known of V(h), we conclude that wetting can be observed only along the gas-liquid phase boundary; however, first-order transitions between thin and thick films, which may be experimentally difficult to distinguish from wetting, can be observed along any phase boundary. The nature of the global phase diagram depends on the form of V(h) and several general behaviors are presented. In particular, in the layering subregime we find that the limit of layering critical points is indeed the bulk roughening temperature as had been suggested by de Oliveira and Griffiths. The scaling of these layering critical points is given explicitly.
机译:在存在硬壁和长距离外部电势V(h)的情况下,采用固体对固体模型研究了吸附膜的生长和可能的润湿行为。使用Migdal近似中的位置空间重新归一化组方法分析该模型。润湿转变的存在及其性质取决于大距离处V(h)的渐近行为。我们发现在该模型中不能发生临界润湿。根据对V(h)的了解,我们得出结论,只能沿气液相边界观察到润湿;然而,沿着任何相位边界都可以观察到薄膜与厚膜之间的一阶跃迁,这在实验上很难与润湿区分开。全局相图的性质取决于V(h)的形式,并给出了几种常规行为。特别地,在分层子区域中,我们发现分层临界点的限制确实是如de Oliveira和Griffiths所建议的整体粗糙化温度。这些分层关键点的缩放比例已明确给出。

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